A Short Method for the Synthesis of Alpha-Tocopherol Side Chain
نویسندگان
چکیده مقاله:
The enzymatic hydrolysis of meso-1,7-diacetoxy-2,6-dimethylheptane 5, prepared from 2,6-dimethylhepta-1,6-diene 6, gave the (2S,6R)-7-acetoxy-2,6-dimethyl-1-heptanol 1, which was transformed to the (2R,6R)-2,6,10-trimethyl-1-undecanol 7. In this manner, the C14 side chain of a-Tocopherol was synthesized from 2,6-dimethylhepta-1,6-diene 6 in only 5 steps.
منابع مشابه
a short method for the synthesis of alpha-tocopherol side chain
the enzymatic hydrolysis of meso-1,7-diacetoxy-2,6-dimethylheptane 5, prepared from 2,6-dimethylhepta-1,6-diene 6, gave the (2s,6r)-7-acetoxy-2,6-dimethyl-1-heptanol 1, which was transformed to the (2r,6r)-2,6,10-trimethyl-1-undecanol 7. in this manner, the c14 side chain of a-tocopherol was synthesized from 2,6-dimethylhepta-1,6-diene 6 in only 5 steps.
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عنوان ژورنال
دوره 26 شماره 4
صفحات 1- 10
تاریخ انتشار 2007-12-01
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